Highly efficient supercapacitor using single-walled carbon nanotube electrodes and ionic liquid incorporated solid gel electrolyte
HIGH PERFORMANCE POLYMERS, vol.30, no.8, pp.971-977, 2018 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 30 Issue: 8
- Publication Date: 2018
- Doi Number: 10.1177/0954008318772333
- Journal Name: HIGH PERFORMANCE POLYMERS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.971-977
- Middle East Technical University Northern Cyprus Campus Affiliated: No
Abstract
Gel polymer electrolyte (GPE) comprising a low viscosity ionic liquid, that is, 1-propyl-3-methyl imidazolium bis(trifluoromethyl sulfonyl)imide (PMI-TFSI, viscosity 38 cP at 20 degrees C) and a polymer, that is, polyvinyl alcohol (PVA) have been prepared using solution cast technique and characterized by impedance spectroscopy, X-ray diffraction, differential scanning calorimetry, optical microscopy, and Fourier transform infrared spectroscopy. Blending PMI-TFSI with PVA matrix hindered the crystallinity of polymer matrix and presented remarkable enhancement in electrical conductivity with a conductivity maxima at 250 wt% PMI-TFSI. The prepared electric double-layer capacitor using single-walled carbon nanotube as symmetric electrodes and PVA:250 wt% PMI-TFSI as GPE presented a capacitance value of about 28 F g(-1).